Suspension polymerization of vinyl chloride initiated by in situ generated diisobutyryl peroxide

281e Kinetic Modeling of the Vinyl Chloride Suspension Polymerization

The physical properties of the polymer product determine to a large extent its processability and applications. A large number of properties are directly related to the molecular mass distribution (MMD) of the polymer product. Besides the MMD, the polymer microstructure also plays an important role and influences to a large extent the thermal stability of the polymer product. Most of the therma...

METHOCEL Cellulose Ethers as Suspending Agents for Suspension Polymerization of Vinyl Chloride

vinyl chloride emulsion polymerization reaction: effect of various formulations

a mixture  of  sodium  lauryl  sulfate  (sls)  as  ionic  emulsifer  and  stearyl alcohol as non-ionic emulsifer was employed in a vinyl chloride emulsion polymerization  reaction  to  study  the  infuence  of  various  interactive parameters involved in the reaction system. it was found that the particle size was dependent on the amount and type of emulsifer. the average particle size of polyv...

poly(vinyl acetate)-based block copolymer/clay nanocomposites prepared by in situ atom transfer radical polymerization

atom transfer radical polymerization of styrene (st) and methyl methacrylate (mma) was performed at 90oc in the absence and presence of nanoclay (cloisite 30b). trichloromethyl-terminated poly(vinyl acetate) telomerand cucl/ pmdeta were used as a macroinitiator and catalyst system, respectively. the experimental results showed that the atom transfer radical polymerization of st and mma in the a...

Photo-Induced Vertical Alignment of Liquid Crystals via In Situ Polymerization Initiated by Polyimide Containing Benzophenone

Vertical alignment of liquid crystal (LC) was achieved in an easy and effective way: in situ photopolymerization of dodecyl acrylate (DA) monomers initiated by polyimide based on 3,3′,4,4′-benzophenonetetracarboxylic dianhydride and 3,3′-dimethyl-4,4′-diaminodiphenyl methane (BTDA-DMMDA PI). The alignment behavior and alignment stabilities were characterized by a polarizing optical microscope (...